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    某画珐琅花卉开光鸟兽图海棠式手炉的腐蚀与防护

    Corrosion and Protection of a Begonia Style Hand Stove of Enamel Flowers and Consecration of Birds and Animals

    • 摘要: 利用便携式显微镜和激光共聚焦显微镜、X射线荧光光谱仪(XRF)、微区X射线衍射分析(μ-XRD)和激光拉曼光谱技术分析方法,对故宫藏画珐琅花卉开光鸟兽图手炉铜盖上出现的锈蚀种类和腐蚀机理进行研究分析,并对器物的整体保存状况予以评估。结果表明:手炉盖基体的主要成分是铜锌合金,采用“金汞齐”方法进行表面鎏金装饰;手炉盖处的锈蚀呈粉末状,锈蚀产物主要是副氯铜矿和斜氯铜矿。采用物理和化学相结合的方法去除了具有潜在危害的锈蚀,并对器物基体进行封护。建议避免使用含氯的水源和酸碱性明显的清洁剂等进行器物的日常除尘保养工作。

       

      Abstract: The types of rust and the corrosion mechanism on the surface of the cover of a hand furnace collected in the Palace Museum's painting of enamel flowers and consecration of birds and animals were analyzed using portable microscopy, laser confocal microscopy, X-ray fluorescence spectrometer (XRF), micro-X-ray diffraction analysis (μ-XRD) and laser Raman spectroscopy analysis methods. The results showed the main component of the base of the hand furnace cover was copper-zinc alloy, and the “gold amalgam” method was used for surface gilt decoration; the rust on the hand stove cover is in powder form, and the rust products were mainly paratacamite and botallackite. Potentially harmful rust was removed by a combination of physical and chemical methods, and the utensil substrate was sealed. It is to avoid using chlorine-containing water sources and detergents with obvious acidity and alkalinity for daily dust removal and maintenance of utensils.

       

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