腐蚀环境中2种典型钛-铝双耳两层结构的腐蚀行为对比
Comparison of Corrosion Behavior of Two Typical Titanium-AluminumDouble-Ear Two-Layer Structures in a Corrosive Environment
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摘要: 对采用不锈钢衬套和铜衬套的2种典型钛-铝双耳两层结构进行了加速腐蚀试验,采用扫描电镜(SEM)和能谱(EDS)分析结构腐蚀形貌、腐蚀产物,对比分析2种结构的耐腐蚀性能。研究表明:在腐蚀环境中,经过10个周期的加速腐蚀试验,2种典型结构均发生了腐蚀疲劳破坏;不锈钢衬套结构的铝合金腐蚀疲劳裂纹形成时间早且断口腐蚀严重,铜衬套周围铝合金的严重腐蚀是诱发该结构腐蚀疲劳损伤的主要原因。推迟疲劳裂纹形成和降低电偶腐蚀等可提高不锈钢衬套结构的耐腐蚀性能,降低结构应力水平、加强结构的日常维护,能有效提高铜衬套结构的耐腐蚀性能。Abstract: Accelerated corrosion tests were carried out on two typical titanium-aluminum double-ear two-layer structures with stainless steel bushing and copper bushing. The corrosion morphology and corrosion products were analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), and the corrosion resistance of the two structures was compared. The results showed that corrosion fatigue damage happened in these two kinds of structures in the corrosive environment. The corrosion fatigue cracks in the aluminum alloy of the structure with stainless steel bushing formed early, and the fracture corroded seriously. The serious corrosion of aluminum alloy near copper bushing was the main reason for inducing corrosion fatigue damage of the structure. Delaying fatigue crack formation and reducing galvanic corrosion could improve the corrosion resistance of the structure with stainless steel bushing. While reducing the stress level of the structure and strengthening the daily maintenance could effectively improve the corrosion resistance of the structure with copper bushing.
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