690TT合金管材在含聚丙烯酸分散剂高温高压环境中的缝隙腐蚀行为
Crevice Corrosion Behavior of 690TT Alloy Tubing in High Temperature and High Pressure Environment with Polyacrylic Acid Dispersant
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摘要: 聚丙烯酸(PAA)可用于核电站蒸汽发生器(SG)二次侧水化学处理以减少腐蚀产物沉积,但PAA在高温下会分解产生小分子有机酸,使SG部件存在加速缝隙腐蚀的风险。采用片状缝隙腐蚀试样及管状缝隙腐蚀试样,在模拟SG高温高压水环境中,开展了PAA对690TT合金管材缝隙腐蚀行为的影响试验。结果表明,添加100 mg/L PAA后,两种缝隙腐蚀试样的腐蚀速率分别下降38%和22%,PAA的添加不会加速690TT合金的缝隙腐蚀。Abstract: In nuclear power facilities, steam generators (SG) can undergo secondary water chemical treatment using polyacrylic acid (PAA) to lessen the deposition of corrosion products. The production of small molecule organic acids by PAA's breakdown at high temperatures, could hasten the corrosion of SG components' crevices. Using sheet-like and tubular crevice corrosion specimens, the impact of PAA on the crevice corrosion behavior of 690TT alloy pipes was examined in a water environment that simulated SG high temperatures and high pressures environment. According to the findings, the corrosion rates of the two kinds of crevice corrosion samples dropped by 38% and 22%, respectively, following the addition of 100 mg/L PAA. The 690TT alloy crevice corrosion was not accelerated by the use of PAA.