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    13Cr和S13Cr钢在煤炭地下气化粗煤气环境中的腐蚀行为

    Corrosion Behavior of 13Cr and S13Cr Steel in Raw Gas from Underground Coal Gasification

    • 摘要: 对13Cr和S13Cr(不锈)钢开展了应力腐蚀开裂试验和腐蚀模拟试验,研究了其在高温高压粗煤气井底工况环境中的应力腐蚀开裂敏感性和腐蚀行为。结果表明,两种试样在550℃、总压10 MPa的含H2、CO2、H2S等气体环境中的应力腐蚀敏感性较低,四点弯试样均未发现宏观开裂和微观裂纹。模拟腐蚀试验结果表明,S13Cr钢的耐蚀性能优于13Cr钢,其均匀腐蚀速率和局部腐蚀速率均低于13Cr钢,根据NACE 0775标准,属于中度腐蚀,且经过模拟腐蚀试验后,两种试样表面未发现高温脱碳现象。

       

      Abstract: Stress corrosion cracking tests and corrosion simulation tests were conducted on 13Cr and S13Cr (stainless) steel to investigate their sensitivity to stress corrosion cracking and corrosion behavior in high-temperature and high-pressure crude gas wellbore conditions. The results show that both samples had low stress corrosion sensitivity in a gas environment containing H2, CO2, H2S, etc. at 550 ℃ and a total pressure of 10 MPa. No macroscopic or microscopic cracks were found in the four point bending samples. The simulated corrosion test results show that the corrosion resistance of S13Cr was better than that of 13Cr, and its uniform corrosion rate and localized corrosion rate were both lower than those of 13Cr. According to the NACE 0775 standard, it belonged to moderate corrosion, and after the simulated corrosion test, no high-temperature decarburization phenomenon was found on the surfaces of the two samples.

       

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