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    青铜文物用封护材料的保护效果评价及紫外光老化机理

    Evaluation of Protective Effect of Coating Materials for Bronze Cultural Relics and Their Ultraviolet Light Aging Mechanism

    • 摘要: 研究了Paraloid B-72(B72)、聚乙烯醇缩丁醛(PVB)、微晶石蜡三种青铜文物封护材料。通过测试三种封护材料的外观变化、成膜性、耐水性、耐酸碱性、耐湿热老化性、耐紫外光老化性能等性能,筛选出最佳的青铜文物封护材料。此外,利用傅里叶变换红外光谱仪,对紫外光老化后的薄膜试样进行分析,探讨其紫外光老化机理。结果表明:B72和微晶石蜡均具有较好的封护性能,PVB则相对较差,但鉴于微晶石蜡的封护操作相对繁琐,且对文物外观影响较大,B72是最适合青铜文物的封护材料;微晶石蜡在紫外光老化过程中只发生了轻微氧化,而B72和PVB均发生了断链和交联反应,内部基团产生了不同程度的变化。

       

      Abstract: Three coating materials for bronze cultural relics were studied, including Paraloid B-72 (B72), polyvinyl butyral (PVB), and microcrystalline wax. By evaluating the appearance change, film-forming properties, water resistance, acid and alkali resistance, damp heat aging resistance, and ultraviolet light aging resistance of the three coating materials, the best coating material for bronze cultural relics was screened out. In addition, using Fourier transform infrared spectrometer, the film samples after ultraviolet light aging were analyzed, so as to explore the mechanism of ultraviolet light aging. The results show that both B72 and microcrystalline wax exhibited good protective performance, while PVB exhibited relatively inferior effectiveness. However, considering that the application of microcrystalline wax was more cumbersome and had a greater impact on the appearance of artifacts, B72 was the most suitable coating material for bronze cultural relics. During the ultraviolet light aging process, the microcrystalline wax underwent slight oxidation, while B72 and PVB both experienced chain breakage and cross-linking reactions, resulting in varying degrees of changes in their internal functional groups.

       

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