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    基于ZIF-7纳米容器的主动腐蚀预警与控制涂层的制备及性能

    Preparation and Properties of Active Corrosion Warning and Control Coating Based on ZIF-7 Nanocontainer

    • 摘要: 将负载罗丹明B酰肼(RBH)的ZIF-7纳米容器(ZID-7@RBH)添加到环氧涂层中,制备了主动腐蚀预警和控制双功能一体化的智能防腐蚀涂层。采用扫描电镜(SEM)、X射线衍射仪(XRD)和傅里叶红外光谱仪(FT-IR)分析了ZIF-7@RBH的微观形貌、结构和化学组成。通过盐雾试验和电化学测试考察了ZIF-7@RBH添加量对涂层耐蚀性的影响。结果表明:制备的纳米容器形貌规整、尺寸均一,并且成功负载了RBH;在涂层中添加0.5%的ZIF-7@RBH能够有效抑制界面腐蚀扩展,该涂层在海水中浸泡20 d后,其低频阻抗模量|Z|0.01 Hz比纯环氧涂层高近一个数量级,显著提升了涂层的防腐蚀性能;破损涂层在海水浸泡20 min后,其缺陷处即可显现荧光,展现出优异的腐蚀自预警效果。

       

      Abstract: A smart anti-corrosion coating with active corrosion warning and control functions was prepared through incorporation of rhodamine B hydrazide (RBH) loaded ZIF-7 nanocontainers (ZIF-7@RBH) into epoxy resin. The micro-morphology, structure and composition of ZIF-7@RBH were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The influence of ZIF-7@RBH addition on the corrosion resistance of epoxy coating was investigated by salt spray and electrochemical tests. The results show that the nanocontainer presented regular morphology and uniform size, and RBH was successfully loaded into the nanocontainer. Addition of 0.5% ZIF-7@RBH into coating was able to effectively inhibit interface corrosion expansion, and after the coating was immersion in seawater for 20 days, the low-frequency impedance modulus |Z|0.01Hz was nearly one order of magnitude higher than that of pure epoxy coating, thus significantly improving the corrosion resistance of the coating. In addition, after the damaged coating soaking in seawater for 20 minutes, obvious fluorescence was observed at the defect, which exhibited excellent corrosion self-reporting effect.

       

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