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    重庆巫山出土带锈鎏金铜器的锈蚀研究

    Survey on the Corrosion of Fire-Gilded Copper Fragments from Wushan District in Chongqing

    • 摘要: 重庆巫山地区近年来出土了大批鎏金铜器,成为巫山博物馆馆藏文物中最具特色的文物。这些鎏金铜器出土时覆盖着一层致密锈蚀,严重影响到其外观和保护处理方式。采用光学显微镜(OM)、扫描电子显微镜(SEM)、激光共聚焦扫描显微镜(LCSM)、X射线衍射(XRD)等表征技术对其中两件残损鎏金铜片进行金相学考察和锈蚀产物分析。结果表明:鎏金铜盘样品基体存在退火孪晶和等轴晶的组织形态,反映铜盘采用了热锻加工成型工艺。锈蚀层存在“三明治”结构特征,鎏金层之下为砖红色赤铜矿锈蚀层,鎏金层之上则覆盖着绿色孔雀石锈蚀层。鎏金层中分布着大量的赤铜矿锈蚀,能够起到锚固增加鎏金层附着力的作用。

       

      Abstract: In recent years, a large number of gilded copper and bronze wares have been excavated from Wushan District in Chongqing, which already become the most famous antiquities in Wushan Museum. Unfortunately, these gilded antiquities were excavated with a thick coating layer of patina to influence their appearance and protective treatments. With the help of various analytical methods such as optical microscopy (OM), scanning electron microscopy (SEM), laser confocal scanning microscopy (LCSM), and X-ray diffraction (XRD), two specimen fragments of gilded bronze were researched on their metallographic and corrosion characteristics. The results show that the metallographic images exhibited the presence of annealing twins and equiaxed crystals corresponding to the hot forging technology to enhance their mechanical strength and corrosion resistance. The rust layer had a sandwich structure feature, with a brick red chalcopyrite rust layer below the gilded layer and a green malachite rust layer covering above the gilded layer. More importantly, the wildly distribution of cuprite rust in the gilded layers acted as anchoring role to enhance their adhesion force.

       

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