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    海洋环境中锈蚀产物纳米压痕与固结试验力学性能

    Mechanical Properties of Corrosion Products in Marine Environment Through Nanoindentation and Consolidation Tests

    • 摘要: 明确实际海洋环境中钢筋锈蚀产物的力学特性对建立混凝土结构锈胀开裂模型具有重要意义。依托海洋基础设施长期性能野外观测研究基地,对实际海洋环境中暴露15 a钢板、预埋钢筋混凝土试块及温州某码头锈胀开裂横梁混凝土构件的锈蚀产物开展了取样及分析工作,通过纳米压痕与固结试验表征了锈蚀产物的纳米压痕弹性模量、硬度及瞬时弹性模量,并进行了微观结构与组成分析。结果表明:钢板锈蚀产物弹性模量低于混凝土中钢筋锈蚀产物,钢筋锈蚀产物弹性模量集中分布于70~110 GPa,硬度为0.002~0.013 GPa;基于Hertz弹性接触理论计算得到的钢筋锈蚀产物瞬时弹性模量集中分布于100~150 GPa;混凝土中钢筋锈蚀产物微观结构较致密,不同锈蚀产物中Fe、O原子比存在较大差异,各锈蚀组分所占比例不同,同时检测到了一定比例的Cl元素,钢筋锈蚀与Cl-的侵蚀紧密相关。

       

      Abstract: Clarifying the mechanical properties of reinforcement corrosion products in marine environments is of great significance for establishing corrosion-induced expansion and cracking models. Relies on the field observation research base of long-term performance of marine infrastructure for transportation industry, the sampling and analysis of reinforcement corrosion products from steel plates and embedded reinforced concrete exposed to marine environments for 15 years, as well as the corrosion-induced expansion and cracking concrete beam components of a pier in Wenzhou were carried out. The nanoindentation elastic modulus, hardness and instantaneous elastic modulus of the corrosion products were characterized through nanoindentation and consolidation tests, and the microstructure and composition were analyzed. The results show that the elastic modulus of corrosion products on steel plate was lower than that of steel corrosion products in concrete. The elastic modulus of steel corrosion products was concentrated in the range of 70-110 GPa, and the hardness was in the range of 0.002-0.013 GPa. Based on the Hertz elastic contact theory, the instantaneous elastic modulus of steel corrosion products was concentrated in the range of 100-150 GPa. The microstructure of steel corrosion products in concrete was relatively dense, and the atomic ratio of Fe and O in different corrosion products was quite different, and the proportion of corrosion components was different. At the same time, a certain proportion of Cl elements was tested, indicating that steel corrosion was closely related to the erosion of Cl-.

       

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