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    HDR钢在海洋环境中的腐蚀行为

    Corrosion Behavior of HDR Steel in Marine Environment

    • 摘要: 依据海洋设备的实际服役条件,采用腐蚀电化学测试、人造海水试验、三亚实海腐蚀试验等方法,研究了HDR钢在海洋环境中的腐蚀行为。结果表明:HDR钢在3.5%(质量分数)NaCl溶液中的自腐蚀电位Ecorr为-0.151 6 V,腐蚀电流密度Jcorr为3.46×10-7 A·cm-2,极化曲线无钝化区;HDR钢在盐雾/干/湿交替循环试验中的腐蚀速率为0.369 0 μm/a,在人造海水中的腐蚀速率为0.374 2 μm/a,在三亚实海中的腐蚀速率从3个月时的0.91 μm/a降至24个月时的0.08 μm/a;综合评价HDR钢耐海水腐蚀性能优异,经过2 a实海腐蚀试验后,HDR钢主要发生了局部腐蚀,可作为现役材料40Cr、2Cr13的替换材料。

       

      Abstract: Based on the actual service conditions of marine equipment, the corrosion behavior of HDR steel in marine environments was studied using methods such as corrosion electrochemical testing, artificial seawater testing, and Sanya real sea corrosion testing. The results show that the self corrosion potential Ecorr of HDR steel in 3.5% (mass fraction) NaCl solution was -0.151 6 V, the corrosion current density Jcorr was 3.46×10-7 A·cm-2, and there was no passivation zone in the polarization curve. The corrosion rate of HDR steel in salt spray/dry/wet alternating cycle test and in artificial seawater was 0.369 0 μm/a and 0.374 2 μm/a respectively, and it decreased from 0.91 μm/a at 3 months to 0.08 μm/a at 24 months in real seawater. The comprehensive evaluation shows that HDR had excellent resistance to seawater corrosion. After 2 a of actual seawater corrosion tests, HDR steel mainly experienced localized corrosion and could be used as a replacement material for the current materials 40Cr and 2Cr13 steel.

       

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