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    改性水滑石的制备及其对砂浆中钢筋锈蚀行为的影响

    Preparation of Modified LDH and Its Effect on Corrosion Behavior of Steel Bar in Mortar

    • 摘要:插层到Zn-Al水滑石(LDH)中制备了改性水滑石,并采用X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)和扫描电镜(SEM)等微观测试手段对其进行了表征;然后,将掺入水泥砂浆中,探究了掺量对水泥砂浆流动性、吸水率、力学性能、孔隙结构、氯离子扩散系数和钢筋阻锈性能的影响。结果表明:对水泥砂浆的吸水率、力学性能、孔隙率和抗氯离子渗透性能均有不同程度的改善,当掺量为3.0%(水泥质量占比,下同)时水泥砂浆性能提升最为显著;当掺量小于3.0%时,砂浆的流动性能有所提升;通过层间离子交换实现对Cl-的吸附,在吸附Cl-过程中伴随着层间的释放;能够有效延缓水泥砂浆中的钢筋锈蚀,且在一定范围内掺量越多,钢筋的耐蚀性越好。

       

      Abstract: A type of modified layered double hydroxide was prepared by intercalating into Zn-Al-LDHs and characterized by means of microscopic testing techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). Then, the was added into cement mortar to investigate the effects of its content on the fluidity, water absorption, mechanical properties, pore structure, chloride diffusion coefficient, and corrosion resistance of the mortar. The test results show that improved the water absorption, mechanical properties, porosity and resistance to chloride ion penetration of the cement mortar to varying degrees, with the most significant enhancement observed in the mortar containing 3.0% (mass percentage in cement) . When the content of was less than 3.0%, the fluidity of mortar was improved. adsorbed Cl- through interlayer ion exchange, accompanied by the release of interlayer during the adsorption of Cl-. effectively delayed the corrosion of steel bars in the cement mortar, and within a certain range, the more the was added, the better the corrosion resistance of bars was.

       

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