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    油水乳化对超临界CO2环境中N80碳钢腐蚀行为的影响

    Effects of Oil-Water Emulsification on Corrosion Behavior of N80 Carbon Steel in Supercritical CO2 Environment

    • 摘要: 在利用高温高压反应釜模拟的超临界CO2/原油/模拟采出水腐蚀环境(CO2压力为9MPa、温度为65℃)中,对N80碳钢进行浸泡腐蚀试验,研究了乳化剂和乳状液含水率对N80碳钢腐蚀速率、腐蚀产物膜微观形貌、腐蚀产物膜元素组成和最大腐蚀深度的影响。通过观察乳化剂加入前后乳状液的形貌,测量原油和模拟采出水在N80碳钢表面接触角的变化,明确油水乳化对超临界CO2腐蚀的影响机理。结果表明:在未添加乳化剂的超临界CO2/原油/模拟采出水体系中N80碳钢的腐蚀速率随着含水率的升高而增大,当含水率小于50%时,N80碳钢发生均匀腐蚀,当含水率大于50%时,N80碳钢发生局部腐蚀;在添加0.5%乳化剂条件下,N80碳钢的腐蚀速率随着含水率的升高而增大,但含水率大于50%后,腐蚀速率变化不大,腐蚀形态都为均匀腐蚀;相同腐蚀环境中,未添加乳化剂条件下N80碳钢的腐蚀速率低于添加0.5%乳化剂条件下的腐蚀速率。乳化剂的加入改变了油水乳状液的性质及其在N80碳钢表面的润湿性,导致N80碳钢在超临界CO2/原油/模拟采出水环境中的腐蚀速率、最大腐蚀深度和腐蚀形貌发生变化。

       

      Abstract: In a supercritical CO2/crude oil/simulated produced water corrosion environment (CO2 pressure of 9 MPa, temperature of 65 ℃) simulated by high temperature and high pressure reactor, immersion corrosion tests were conducted on N80 carbon steel to investigate the effects of emulsifier and water content in emulsions on the corrosion rate, microscopic morphology of corrosion product films, elemental composition of corrosion product films, and maximum corrosion depth of N80 carbon steel. By observing the morphology of emulsions before and after adding emulsifiers and measuring changes in the contact angles of crude oil and simulated produced water on the surface of N80 carbon steel, the influence mechanism of oil-water emulsification on supercritical CO2 corrosion was determined. The results show that under emulsifier-free condition, the corrosion rate of N80 carbon steel in the supercritical CO2/crude oil/simulated produced water system increased with rising water content. When the water content was below 50%, uniform corrosion occurred in N80 carbon steel, whereas localized corrosion developed when the water content exceeded 50%. Under the condition of 0.5% emulsifier addition, the corrosion rate of N80 carbon steel increased with rising water content. However, when the water content exceeded 50%, the corrosion rate remained relatively stable, and uniform corrosion was observed throughout all water content levels. Under identical corrosive conditions, N80 carbon steel exhibited lower corrosion rates without emulsifier addition compared to cases with 0.5% emulsifier. The introduction of emulsifiers altered both the properties of oil-water emulsions and their wettability on N80 steel surfaces, consequently modifying the corrosion rate, maximum corrosion depth, and corrosion morphology in supercritical CO2/crude oil/simulated produced water environment.

       

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