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    唐代瑞兽纹铜镜的腐蚀特征及保护对策

    Corrosion Characteristics and Conservation Measures of the Tang Dynasty Bronze Mirror with Auspicious Beast Motifs

    • 摘要: 利用X射线探伤仪、扫描电镜能谱仪(SEM-EDS)、光学显微镜及拉曼光谱仪等分析手段,对一件唐代瑞兽纹铜镜的基体成分及腐蚀产物进行系统表征,以研究其腐蚀特征。结果表明:在长期埋藏过程中,铜镜由表及里形成了多层腐蚀结构,其表层腐蚀产物主要为Cu2(OH)2CO3、Cu2(OH)3Cl及微量PbSO4;基体金属的腐蚀呈现明显相选择性,其中铅及(α+δ)共析体相较α固溶体相优先发生腐蚀,这一腐蚀特征与其埋藏环境存在显著相关性。基于腐蚀特征分析,对该铜镜提出了保护修复建议。

       

      Abstract: The corrosion characteristics of a Tang Dynasty bronze mirror with auspicious beast motifs were systematically investigated using X-ray flaw detectors, scanning electron microscopy energy dispersive spectroscopy (SEM-EDS), optical microscopey, and Raman spectrometers to analyze its substrate composition and corrosion products. The results show that during long-term burial, a multilayer corrosion structure gradually formed from the surface inward. The surface corrosion products mainly consisted of Cu2(OH)2CO3, Cu2(OH)3Cl, and trace amounts of PbSO4. The substrate metal exhibited distinct phase-selective corrosion, where lead and (α+δ) eutectoid were preferentially corroded compared to the α phase. This corrosion characteristic showed a significant correlation with its burial environment. Based on the analysis of corrosion characteristics, conservation and restoration recommendations were proposed for the bronze mirror.

       

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