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    压水堆一回路水化学工况下SiC/SiCf复合材料包壳管的腐蚀行为

    Corrosion Behavior of SiC/SiCf Composite Cladding Tubes Under PWR Primary Circuit Water Chemistry Conditions

    • 摘要: 采用循环可控水化学系统模拟压水堆核电站一回路水环境,针对SiC/SiCf复合材料包壳管开展高温高压水腐蚀试验。通过质量损失、微观形貌、成分分析等研究了带有CVD(化学气相沉积)-SiC涂层的SiC/SiCf复合材料包壳管在高温高压环境中的腐蚀行为。结果表明:SiC/SiCf复合材料包壳管在高温高压水环境中经历了腐蚀质量增加阶段、腐蚀质量增加-质量降低过渡阶段、腐蚀质量降低阶段。在腐蚀质量增加阶段,氧化物颗粒及团簇不断生长连结并形成氧化膜,减少了基体与高温高压水接触的面积,减缓了SiC的腐蚀溶解;在腐蚀质量增加-质量降低过渡阶段,氧化物颗粒或者氧化物团簇逐渐消失,表面可见密集的角状晶裸露以及腐蚀坑,SiC在高温高压水中开始以腐蚀溶解为主;在腐蚀质量降低阶段,SiC外涂层表面平整,没有发现腐蚀坑,腐蚀速率基本保持稳定。

       

      Abstract: A recirculating controlled water chemistry system was employed to simulate the primary circuit water environment of a pressurized water reactor (PWR). High-temperature and high-pressure water corrosion tests were conducted on SiC/SiCf composite cladding tubes. The corrosion performance was investigated through mass change measurements, microscopic morphology analysis, and composition characterization. The results indicate that the corrosion process of SiC/SiCf composite cladding tubes in high-temperature high-pressure water could be divided into three distinct stages: a corrosion mass gain stage, a transition stage (mass gain to mass loss), and a corrosion mass loss stage. During the corrosion mass gain stage, oxide particles and clusters continuously grew and interconnected, forming an oxide film that reduced the contact area between the substrate and the high-temperature high-pressure water, thereby slowing down the corrosion dissolution of SiC. In the transition stage (mass gain to mass loss), oxide particles or clusters gradually disappeared, exposing angular crystals and corrosion pits on the surface, indicating that the dominant mechanism shifted to SiC dissolution in high-temperature high-pressure water. In the corrosion mass loss stage, the surface of the SiC outer coating became smooth, with no visible corrosion pits, and the corrosion rate was stable.

       

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