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    热裂解-气质联用技术在室外大型金属雕塑防护涂层成分分析中的应用

    Application of Py-GC/MS in Composition Analysis of Protective Coatings for Outdoor Large Metal Sculptures

    • 摘要: 华北军区烈士陵园《胜利》组雕经过70余a室外展示,其表面存在污渍、锈蚀产物、防护涂层老化等多种病害。为了更科学地了解当年制作《胜利》组雕时使用的防护材料及制作工艺,采用X射线衍射(XRD)、傅里叶变换红外(FTIR)和热裂解-气相色谱/质谱技术(Py-GC/MS)等分析了该雕塑的防护涂层材料。结果表明:《胜利》组雕制作时使用了油漆涂料作为有机防护涂层,通过分析获得了成膜物质、溶剂、颜料及助剂等涂料组分,为认识《胜利》组雕的涂装制作工艺和实施保护提供科学依据。

       

      Abstract: After more than 70 years of outdoor display, there are various diseases such as stains, corrosion products, and aging materials on the surface of the “Victory” group sculptures in the North China Military Martyrs Cemetery. To understand the protective materials and production processes used in the creation of the “Victory” sculptures, the materials of protective coating on the sculptures were analyzed by X-ray diffraction (XRD), Fourier transform infrared (FTIR) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The results show that during the creation of the “Victory” sculptural group, paint was used as an organic protective coating. Analysis revealed four components of the paint: film-forming substances, solvents, pigments, and additives. This provides a scientific basis for understanding the painting techniques employed in the “Victory” group sculptures and for implementing their conservation.

       

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