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    高温高压水中扩散氢对9Cr-ODS钢冷却管表面氧化膜的影响

    Effect of Diffused Hydrogen on Surface Oxide Film of 9Cr-ODS steel Cooling Tubes in High Temperature and High Pressure Water

    • 摘要: 基于聚变堆内包层冷却管运行工况,研究了动态扩散氢对9Cr-ODS钢薄壁管在高温高压(325 ℃/15.5 MPa)除氧水中腐蚀400 h后氧化膜的影响。结果表明:9Cr-ODS钢表面氧化膜均为双层结构,内层为(Fe,Cr)2O4和Cr2O3,外层为Fe3O4;扩散氢使得氧化膜稳定性变差,氧化膜表面产生缺陷和裂纹,界面渗透现象不明显。

       

      Abstract: Based on the operating conditions of the cooling tubes in the fusion reactor blanket, the effect of dynamic diffusible hydrogen on the oxide film of 9Cr-ODS steel thin-walled tubes was investigated after 400 h corrosion in high-temperature high-pressure (325 ℃/15.5 MPa) deoxygenated water. The results indicate that a dual-layer structure was exhibited by the oxide film on 9Cr-ODS steel, with the inner layer composed of (Fe, Cr)2O4 and Cr2O3 and the outer layer consisting of Fe3O4. The stability of the oxide film was reduced by diffusible hydrogen, with defects and cracks generated on its surface, while no significant interfacial penetration was observed.

       

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