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    熔融太阳盐中金属氧化物纳米颗粒对304不锈钢的防护效果

    Protection Effects of Metal Oxide Nanoparticles in Molten Solar Salt on Corrosion of 304 Stainless Steel

    • 摘要: 采用腐蚀增重法和表面分析技术研究了模拟熔融太阳盐中Al2O3,CuO,ZnO,TiO2,SnO2等五种纳米颗粒对太阳盐储罐材料304不锈钢腐蚀的影响。结果表明:304不锈钢浸渍在含与不含纳米颗粒的熔融太阳盐中均出现腐蚀增重现象。Al2O3,CuO,ZnO,TiO2,SnO2等五种纳米颗粒的加入会均对304不锈钢的腐蚀增重产生抑制作用,抑制效果由大到小依次为Al2O3>ZnO>CuO>TiO2>SnO2。在熔融太阳盐中,纳米金属氧化物颗粒可在不锈钢表面形成良好的保护膜,除了与纳米颗粒在不锈钢表面氧化层形成物理掺杂以外,发生化学掺杂是更重要的影响因素。

       

      Abstract: The effect of five kinds of nano particles Al2O3, CuO, ZnO, TiO2 and SnO2 in simulated molten solar salt on corrosion of 304 stainless steel used as solar salt storage tank material was studied by corrosion weight gain method and surface analysis technology. The results showed that all the 304 stainless steel samples immersed in molten solar salt with or without nano particles had corrosion and weight gain. The addition of Al2O3, CuO, ZnO, TiO2 and SnO2 nano particles could inhibit the corrosion of 304 stainless steel, and the inhibition effect rank was Al2O3, ZnO, CuO, TiO2 and SnO2 in turn. In molten solar salt, the nano metal oxide particles could form a good protective film on the stainless steel surface. In addition to forming physical doping with nano particles on the stainless steel surface oxide layer, chemical doping was a more important factor.

       

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