• 中国核心期刊（遴选）数据库收录期刊
  • 中国科技论文统计源期刊
  • 中国学术期刊综合评价数据库来源期刊
Advanced Search
LI Guang-zhou, CHEN Lin-hua, ZHANG Yao, CHANG Hui, DING Yi, MENG Xian-hu. Effects of H2S on Corrosion Behavior of Carbon Steel in Simulated Oil Storage Tank Bottom Solution[J]. Corrosion & Protection, 2017, 38(2): 129-133. DOI: 10.11973/fsyfh-201702009
Citation: LI Guang-zhou, CHEN Lin-hua, ZHANG Yao, CHANG Hui, DING Yi, MENG Xian-hu. Effects of H2S on Corrosion Behavior of Carbon Steel in Simulated Oil Storage Tank Bottom Solution[J]. Corrosion & Protection, 2017, 38(2): 129-133. DOI: 10.11973/fsyfh-201702009
shu

Effects of H2S on Corrosion Behavior of Carbon Steel in Simulated Oil Storage Tank Bottom Solution

  • 1. College of Material Science and Engineering, Nanjing University of Technology, Nanjing 210009, China;

  • 2. BASF-YPC Co., Ltd., Nanjing 210048, China;

  • 3. Jiangsu Zhongxin Pipe Sci-tec Co., Ltd., Nanjing 210041, China

More Information
  • Received Date: October 07, 2015
    Graphical Abstract
    • Abstract
  • The corrosion behavior of Q235 carbon steel in simulated solution containing H2S was investigated using the methods of weight loss, electrochemical measurement, scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results show that the increase of H2S concentration promoted hydrogen evolution reaction, so the corrosion rate of carbon steel increased. The loose and porous corrosion products formed on the steel surface were composed of mackinawite. The corrosion products of carbon steel, which was corroded in sequence in the solution containing H2S and in the solution containing dissolved oxygen but without H2S, were divided into two layers. The inner layer was still mainly composed of mackinawite and the outer layer was oxidation product. The oxidation product led to the rupture and shedding of ferrous sulfide film. The existence of ferrous sulfide film provided more protection to carbon steel in the solution containing H2S than in the solution containing oxygen.
    • FullText(HTML)
    • References (24)
  • [1]
    FOROULIS Z A. Causes,mechanisms and prevention of internal corrosion in storage tanks for crude oil and distillates[J]. Anti-Corrosion Methods and Materials,1981,28(9):4-9.
    [2]
    GROYSMAN A. Corrosion in systems for storage and transportation of petroleum products and biofuels:identification,monitoring and solutions[M].[S.l.]:Springer Science & Business Media,2014:65-107.
    [3]
    董娇,李青蕊. 储罐底板的腐蚀与防护[J]. 广东化工,2013,40:129-130.
    [4]
    王菁辉. 钢质石油储罐防腐蚀工程[M]. 北京:中国石化出版社,2011:6-9.
    [5]
    MA H,CHENG X,LI G,et al. The influence of hydrogen sulfide on corrosion of iron under different conditions[J]. Corrosion Science,2000,42(10):1669-1683.
    [6]
    ARZOLA S,GENESCÁ J. The effect of H2S concentration on the corrosion behavior of API 5L X-70 steel[J]. Journal of Solid State Electrochemistry,2005,9(4):197-200.
    [7]
    TANG J W,SHAO Y W,GUO J B,et al. The effect of H2S concentration on the corrosion behavior of carbon steel at 90℃[J]. Corrosion Science,2010,52(6):2050-2058.
    [8]
    TAHERI H,KAKOOEI S,ISMAIL M C,et al. The effect of H2S concentration and temperature on corrosion behavior of pipeline steel A516-Gr70[J]. Caspian Journal of Applied Sciences Research,2012,1(5):41-47.
    [9]
    QI Y,LUO H,ZHENG S,et al. Effect of temperature on the corrosion behavior of carbon steel in hydrogen sulphide environments[J]. International Journal of Electrochemical Science,2014,9(4):2101-2112.
    [10]
    LI D,ZHANG L,YANG J,et al. Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2[J]. International Journal of Minerals,Metallurgy,and Materials,2014,21(4):388-394.
    [11]
    ABELEV E,RAMANARAYANAN T A,BERNASEK S L. Iron corrosion in CO2/brine at low H2S concentrations:an electrochemical and surface science study[J]. Journal of the Electrochemical Society,2009,156(9):331-339.
    [12]
    SMITH S N,JOOSTEN M W. Corrosion of carbon steel by H2S in CO2 containing oilfield environments[C]//Corrosion 2006.[S.l.]:NACE International,2006.
    [13]
    MORRIS D R,SAMPALEANU L P,VEYSEY D N. The corrosion of steel by aqueous solutions of hydrogen sulfide[J]. Journal of the Electrochemical Society,1980,127(6):1228-1235.
    [14]
    MEYER F H,RIGGS O L,MCGLASSON R L,et al. Corrosion products of mild steel in hydrogen sulfide environments[J]. Corrosion,1958,14(2):69-75.
    [15]
    SMITH J S,MILLER J D A. Nature of sulphides and their corrosive effect on ferrous metals:a review[J]. British Corrosion Journal,1975,10(3):136-143.
    [16]
    MENENDEZ C M,JOVANCICEVIC V,RAMACHANDRAN S,et al. Assessment of corrosion under iron sulfide deposits and CO2/H2S conditions[J]. Corrosion,2012,69(2):145-156.
    [17]
    LYUBLINSKI E,KUZNETSOV Y I,SCHULTZ M,et al. Corrosion protection of tank product side bottoms[J]. International Journal of Corrosion and Scale Inhibition,2013,2(2):150-161.
    [18]
    VELOZ M A,GONZALEZ I. Electrochemical study of carbon steel corrosion in buffered acetic acid solutions with chlorides and H2S[J]. Electrochimica Acta,2002,48(2):135-144.
    [19]
    FATAH M C,ISMAIL M C,ARI-WAHJOEDI B,et al. Effects of sulphide ion on the corrosion behaviour of X52 steel in a carbon dioxide environment at temperature 40℃[J]. Materials Chemistry and Physics,2011,127(1):347-352.
    [20]
    SHOESMITH D W,TAYLOR P,BAILEY M G,et al. The formation of ferrous monosulfide polymorphs during the corrosion of iron by aqueous hydrogen sulfide at 21℃[J]. Journal of the Electrochemical Society,1980,127(5):1007-1015.
    [21]
    SUN W,NEŠIC S,YOUNG D,et al. Equilibrium expressions related to the solubility of the sour corrosion product mackinawite[J]. Industrial & Engineering Chemistry Research,2008,47(5):1738-1742.
    [22]
    VEDAGE H,RAMANARAYANAN T A,MUMFORD J D,et al. Electrochemical growth of iron sulfide films in H2S-saturated chloride media[J]. Corrosion,1993,49(2):114-121.
    [23]
    杨怀玉,陈家坚. H2S水溶液中的腐蚀与缓蚀作用机理的研究:Ⅰ. 酸性H2S溶液中碳钢的腐蚀行为及硫化物膜的生长[J]. 中国腐蚀与防护学报,2000,20(1):1-7.
    [24]
    邹妍. 海水中锈层覆盖碳钢的腐蚀电化学行为研究[D]. 青岛:中国海洋大学,2010:15-17.
    • Related Articles

Catalog

    Get Citation
    PDF
    XML
    Article views (2) PDF downloads (3) Cited by()
    Turn off MathJax
    Article Contents
    Abstract
    References

    Corrosion & Protection

    Address：99 Handan Road, ShanghaiPost Code: 200437

    Tel：021-65556775-290Email:cp@mat-test.com

    沪ICP备17055736号-5

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return