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WU Jin, LUO Lan, LIU Yong, XIONG Tinghui. Research Progress on Corrosion Resistance of Mg-Al Magnesium Alloy[J]. Corrosion & Protection, 2018, 39(9): 651-657. DOI: 10.11973/fsyfh-201809001
Citation: WU Jin, LUO Lan, LIU Yong, XIONG Tinghui. Research Progress on Corrosion Resistance of Mg-Al Magnesium Alloy[J]. Corrosion & Protection, 2018, 39(9): 651-657. DOI: 10.11973/fsyfh-201809001
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Research Progress on Corrosion Resistance of Mg-Al Magnesium Alloy

  • Key Laboratory of Lightweight and High Strength Structural Materials of Jiangxi Province, School of Materials Science and Engineering, Nanchang University, Nanchang 330001, China

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  • Received Date: March 19, 2017
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    • Abstract
  • Magnesium alloys as a green light structural materials are widely used in industry. However, the poor corrosion resistance is a challenge which limits their wider application. Mg-Al series alloys exhibit better corrosion properties, as compared with other Mg alloys. The corrosion characteristics and mechanism of Mg-Al binary alloy are introduced. The influence of alloying elements on the corrosion performance is analyzed. The effects of heat treatment and deformation, especially hot rolling and extrusion deformation on the corrosion resistance of Mg-Al alloy are discussed. The advantages and disadvantages of the commonly used protective technology on the surface of Mg-Al alloy are reviewed.
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  • [1]
    JOOST W J,KRAJEWSKI P E. Towards magnesium alloys for high-volume automotive applications[J]. Scripta Materialia,2017,128:107-112.
    [2]
    KIANI M,GANDIKOTA I,RAIS-ROHANI M,et al. Design of lightweight magnesium car body structure under crash and vibration constraints[J]. Journal of Magnesium & Alloys,2014(2):99-108.
    [3]
    任兰柱,董瑞君,徐洪,等. 镁合金在汽车车身上的应用研究[J]. 热加工工艺,2016,45(10):30-32.
    [4]
    孙伯勤. 镁合金压铸件在汽车行业中的巨大应用潜力[J]. 特种铸造及有色合金,1998(3):40-41.
    [5]
    刘长瑞,王伯建,胡裕邦. 镁合金材料在电子行业的开发应用前景[J]. 铝镁通讯,2001(2):53-55.
    [6]
    彭暄,朱元清,徐文敏. 镁合金在电子产品外设的应用[J]. 机械工业杂志(台湾),1999(1):170-180.
    [7]
    李玉兰,刘江,彭晓东. 镁合金压铸件在汽车上的应用[J]. 特种铸造及有色合金,1999(1):120.
    [8]
    陈晓阳,曾大本. 镁合金铸件的应用现状及发展前景[J]. 铸造,1999(11):53-54.
    [9]
    刘正,王越,王中光,等. 镁基轻质材料的研究与应用[J]. 材料研究学报,2000,14(5):449-456.
    [10]
    LIU L J,SCHLESINGER M. Corrosion of magnesium and its alloys[J]. Corrosion Science,2009,51(8):1733-1737.
    [11]
    SHI Z,LIU M,ATRENS A. Measurement of the corrosion rate of magnesium alloys using tafel extrapolation[J]. Corrosion Science,2010,52(2):579-588.
    [12]
    BRADY M P,FAYEK M,ELSENTRIECY H H,et al. Tracer film growth study of hydrogen and oxygen from the corrosion of magnesium in water[J]. Journal of the Electrochemical Society,2014,161(9):C395-C404.
    [13]
    UNOCIC K A,ELSENTRIECY H H,BRADY M P,et al. Transmission electron microscopy study of aqueous film formation and evolution on magnesium alloys[J]. Journal of the Electrochemical Society,2014,161(6):C302-C311.
    [14]
    BRADY M P,ROTHER G,ANOVITZ L M,et al. Film breakdown and nano-porous Mg(OH)2 formation from corrosion of magnesium alloys in salt solutions[J]. Journal of the Electrochemical Society,2015,162(4):140-149.
    [15]
    HARA N,KOBAYASHI Y,KAGAYA D,et al. Formation and breakdown of surface films on magnesium and its alloys in aqueous solutions[J]. Corrosion Science,2007,49(1):166-175.
    [16]
    SONG G,BOWLES A L,STJOHN D H. Corrosion resistance of aged die cast magnesium alloy AZ91D[J]. Materials Science & Engineering A,2004,366(1):74-86.
    [17]
    SONG G,ATRENS A,WU X,et al. Corrosion behaviour of AZ21,AZ501 and AZ91 in sodium chloride[J]. Corrosion Science,1998,40(10):1769-1791.
    [18]
    WEI L Y,WESTENGEN H,AUNE T K,et al. Magnesium technology 2000[M]. Warrendale,Pa:TMS,2000:153.
    [19]
    LUNDER O,LEIN J E,AUNE T K,et al. The role of Mg17Al12 phase in the corrosion of Mg alloy AZ91[J]. Corrosion,1989,45(9):741-748.
    [20]
    HERMANN F,SOMMER F,JONES H,et al. Corrosion inhibition in magnesium-aluminium-based alloys induced by rapid solidification processing[J]. Journal of Materials Science,1989,24(7):2369-2379.
    [21]
    ZENG R,ZHANG J,HUANG W,et al. Review of studies on corrosion of magnesium alloys[J]. Transactions of Nonferrous Metals Society of China,2006,16:763-771.
    [22]
    SINGH R R K. The role of microstructure in localized corrosion of magnesium alloys[J]. Metallurgical and Materials Transactions A,2004,35(8):2525-2531.
    [23]
    白力静,张华,袁颖,等. β-Mg17Al12相含量对AZ91镁合金腐蚀行为的影响[J]. 西安大理工学学报,2011,27(1):31-35.
    [24]
    SONG G L,ATRENS A. Corrosion mechanisms of magnesium alloys[J]. Advanced Engineering Materials,1999,1(1):11-33.
    [25]
    范晓明,万朋,文红艳. Mn含量对含铁AZ91D镁合金铸态组织与性能的影响[J]. 中国铸造装备与技术,2008(6):16-18.
    [26]
    陈先华,王敬丰,汤爱涛,等. 杂质元素对镁合金组织与性能的影响及其对应措施[J]. 材料导报,2010,24(3):37-41.
    [27]
    ESMAILY M,BLVCHER D B,SVENSSON J E,et al. New insights into the corrosion of magnesium alloys-the role of aluminum[J]. Scripta Materialia,2016,115:91-95.
    [28]
    高慧. 适用于镁合金的高效缓蚀剂的研究[D]. 重庆:西南大学,2011.
    [29]
    MÖ P,MM A. Magnesium alloying,some potentials for alloy development[J]. Journal of Japan Institute of Light Metals,1992,42(12):679-686.
    [30]
    GARBOGGINI A,MCSHANE H B. Effect of zinc and silicon additions on structure and properties of rapidly solidified Mg-Al alloys[J]. Materials Science and Technology,1994,10(9):763-770.
    [31]
    FENG H,LIU S,DU Y,et al. Effect of the second phases on corrosion behavior of the Mg-Al-Zn alloys[J]. Journal of Alloys and Compounds,2017,695:2330-2338.
    [32]
    MAKAR G L,KRUGER J. Corrosion studies of rapidly solidified magnesium alloys[J]. Journal of the Electrochemical Society,1990,137(2):414-421.
    [33]
    TSUCHIYA T,WATANABE K,MATSUDA K,et al. Effect of Al and Mn contents on microstructure in AM-series magnesium alloys[J]. Advanced Materials Research,2011,409:358-361.
    [34]
    薛俊峰. 镁合金防腐蚀技术[M]. 北京:化学工业出版社,2010.
    [35]
    张诗昌,段汉桥,蔡启舟,等. 主要合金元素对镁合金组织和性能的影响[J]. 铸造,2001,50(6):310-315.
    [36]
    MATSUBARA H,ICHIGE Y,FUJITA K,et al. Effect of impurity Fe on corrosion behavior of AM50 and AM60 magnesium alloys[J]. Corrosion Science,2013,66:203-210.
    [37]
    宋佩维. 往复挤压Mg-Al-Si合金的组织、性能及强化机制[D]. 西安:西安理工大学,2007.
    [38]
    LI G Q,WU G H,FAN Y,et al. Effect of the main alloying elements on microstructure and corrosion resistance of magnesium alloys[J]. Zhuzao Jishu (Foundry Technology),2006,27(1):79-83.
    [39]
    LUNDER O,NISANCIOGLU K,HANSEN R S. Corrosion of die cast magnesium-aluminum alloys[R]. SAE Technical Paper,1993.
    [40]
    HILLIS J E,SHOOK S O. Composition and performance of an improved magnesium AS41 alloy[R]. SAE Technical Paper,1989.
    [41]
    WEI L Y. Development of microstructure in cast magnesium alloys[D]. Goteborg:Chalmers University of Technology,1990.
    [42]
    张芳君. 合金化元素对镁合金耐蚀性能的影响[D]. 重庆:重庆大学,2012.
    [43]
    王喜峰,齐公台. 混合稀土对AZ91镁合金在NaCl溶液中腐蚀行为的影响[J]. 材料开发与应用,2002,17(5):34-36.
    [44]
    段汉桥,王立世,蔡启舟,等. 稀土对AZ91镁合金耐腐蚀性能的影响[J]. 中国机械工程,2003,14(20):1789-1793.
    [45]
    ZHOU W,SHEN T,AUNH N N. Effect of heat treatment on corrosion behaviour of magnesium alloy AZ91D in simulated body fluid[J]. Corrosion Science,2010,52(3):1035-1041.
    [46]
    NEIL W C,FORSYTH M,HOWLETT P C,et al. Corrosion of heat treated magnesium alloy ZE41[J]. Corrosion Science,2011,53(10):3299-3308.
    [47]
    SONG G,ATRENS A,DARGUSCH M. Influence of microstructure on the corrosion of die cast AZ91D[J]. Corrosion Science,1998,41(2):249-273.
    [48]
    RALSTON K D,BIRBILIS N,DAVIES C H J. Revealing the relationship between grain size and corrosion rate of metals[J]. Scripta Materialia,2010,63(12):1201-1204.
    [49]
    CAO F,SONG G L,ATRENS A. Corrosion and passivation of magnesium alloys[J]. Corrosion Science,2016,111:835-845.
    [50]
    LIAO H,ZHOU X,LI H,et al. Effect of aging time on corrosion behavior of as-forged AZ80 magnesium alloy[J]. Transactions of Nonferrous Metals Society of China,2015,25(12):3921-3927.
    [51]
    SONG G L,XU Z Q. The surface, microstructure and corrosion of magnesium alloy AZ31 sheet[J]. Electrochimica Acta,2010,55(13):4148-4161.
    [52]
    苏丽新. 热处理工艺对压铸镁合金AM50性能的影响[D]. 长春:长春工业大学,2016.
    [53]
    JIAO Y F,ZHANG J H,HE L L,et al. Al-RE intermetallic phase stability and effects on corrosion behavior in cold-chamber HPDC AE44 alloy[J]. Advanced Engineering Materials,2015,18(1):148-155.
    [54]
    SU M L,ZHANG J,FENG Y,et al. Al-Nd intermetallic phase stability and its effects on mechanical properties and corrosion resistance of HPDC Mg-4Al-4Nd-0.2 Mn alloy[J]. Journal of Alloys and Compounds,2017,691:634-643.
    [55]
    GU X,ZHENG Y,CHENG Y,et al. In vitro corrosion and biocompatibility of binary magnesium alloys[J]. Biomaterials,2009,30(4):484-498.
    [56]
    WANG H,ESTRIN Y,FU H,et al. The effect of pre-processing and grain structure on the bio-corrosion and fatigue resistance of magnesium alloy AZ31[J]. Advanced Engineering Materials,2007,9(11):967-972.
    [57]
    CAO F,SHI Z,SONG G L,et al. Influence of hot rolling on the corrosion behavior of several Mg-X alloys[J]. Corrosion Science,2015,90:176-191.
    [58]
    SONG G L. The effect of texture on the corrosion behavior of AZ31 Mg alloy[J]. JOM,2012,64(6):671-679.
    [59]
    LIU M,UGGOWITZER P J,NAGASEKHAr A V,et al. Calculated phase diagrams and the corrosion of die-cast Mg-Al alloys[J]. Corrosion Science,2009,51(3):602-619.
    [60]
    KIM H S,KIM G H,KIM H,et al. Enhanced corrosion resistance of high strength Mg-3Al-1Zn alloy sheets with ultrafine grains in a phosphate-buffered saline solution[J]. Corrosion Science,2013,74(3):139-148.
    [61]
    ZHANG Z M,XU H Y. Corrosion and mechanical properties of hot-extruded AZ31 magnesium alloys[J]. Transactions of Nonferrous Metals Society of China,2008,18:140-144.
    [62]
    ZHANG T,SHAO Y,MENG G,et al. Corrosion of hot extrusion AZ91 magnesium alloy:I-relation between the microstructure and corrosion behavior[J]. Corrosion Science,2011,53(5):1960-1968.
    [63]
    BEN-HAROUSH M,BEN-HAMU G,ELIEZER D,et al. The relation between microstructure and corrosion behavior of AZ80 Mg alloy following different extrusion temperatures[J]. Corrosion Science,2008,50(6):1766-1778.
    [64]
    赵立新,顾云飞,邵忠财,等. 镁合金无铬化学转化膜的研究现状及发展趋势[J]. 电镀与涂饰,2009,28(1):33-36.
    [65]
    朱青,朱明,余勇,等. AZ91D镁合金Mo-Mn无铬转化膜的制备与耐蚀性[J]. 表面技术,2015,44(8):9-14.
    [66]
    LIU C,LIANG J,ZHOU J,et al. Effect of laser surface melting on microstructure and corrosion characteristics of AM60B magnesium alloy[J]. Applied Surface Science,2015,343:133-140.
    [67]
    TRUONG V T,LAI P K,MOORE B T,et al. Corrosion protection of magnesium by electroactive polypyrrole/paint coatings[J]. Synthetic Metals,2000,110(1):7-15.
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