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ZHANG Ziyue, YU Gangqiang, JIANG Sheming, GAO Zhiqiang, LIU Xin. Film Formation Mechanism of Vanadium Oxide Conversion Coating on Hot-dip Galvanizing Layer[J]. Corrosion & Protection, 2019, 40(5): 370-373,378. DOI: 10.11973/fsyfh-201905012
Citation: ZHANG Ziyue, YU Gangqiang, JIANG Sheming, GAO Zhiqiang, LIU Xin. Film Formation Mechanism of Vanadium Oxide Conversion Coating on Hot-dip Galvanizing Layer[J]. Corrosion & Protection, 2019, 40(5): 370-373,378. DOI: 10.11973/fsyfh-201905012

Film Formation Mechanism of Vanadium Oxide Conversion Coating on Hot-dip Galvanizing Layer

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  • Received Date: November 19, 2017
  • Scanning electron microscope was used to observe the micro morphology of conversion coating in the process of nucleation and growth, the mass of conversion coating was tested by chemical method, and XPS was used to analyze the compound ingredients of the conversion coating. The results show that the vanadium acid salt conversion films were mainly composed of low vanadium compound deposition and vanadium and zinc salt crystals grown up. The weight of conversion film increased with increasing the content of sodium metavanadate within a certain range, which indicated that vanadate passivation had great potential for surface treatment of hot dip galvanized coating.
  • [1]
    CHEN X B,BIRBILIS N,ABBOTT T B,et al. Review of corrosion-resistant conversion coatings for magnesium and its alloys[J]. Corrosion,2011,67(3):1-15.
    [2]
    RALSTON K D,CHRISANTI S,YOUNG T L,et al. Corrosion inhibition of aluminum alloy 2024-T3 by aqueous vanadium species[J]. Journal of the Electrochemical Society,2008,155(7):350-359.
    [3]
    NIU L Y,CHANG S Y H,TONG X,et al. Analysis of characteristics of vanadate conversion coating on the surface of magnesium alloy[J]. Jounal of Alloys and Compounds,2014(617):214-218.
    [4]
    GUAN H,BUCHHEIT R G. Corrosion protection of aluminum alloy 2024-T3 by vanadate conversion coatings[J]. Corrosion,2004(60):284-296.
    [5]
    YANG K H,GER M D,WU W H H,et al. Study of vanadium-based chemical conversion coating on the corrosion resistance of magnesium alloy[J]. Materials Chemistry and Physics,2007(101):480-485.
    [6]
    TEDIM J,ZHELUDKEVICH M L,BASTOS A C,et al. Influence of preparation conditions of layered double hydroxide conversion films on corrosion protection[J]. Electromagnetic,2014(117):164-171.
    [7]
    BIESTEK T,WEBER J. Electrolytic and chemical conversion coatings[M]. Warsa:Wydawnictwa Naukowo-Techniczne,1976:10-11.
    [8]
    MASAAKI Y,TAKAFUMI Y,AKIRA M,et al. NKK galvalume steel sheet:genius coat[J]. NKK Technical Review,2000(83):37-41.
    [9]
    NAZAROV A,THIERRY D,PROSEK T,et al. Protective action of vanadate at defected areas of organic coatings on zinc[J]. Journal of The Electrochemical Society,2005,152(7):220-227.
    [10]
    ZOU Z L,LI N,LI D Y,et al. A vanadium-based conversion coating as chromate replacement for electro galvanized steel substrates[J]. Journal of Alloys and Compounds,2011,509(2):503-507.
    [11]
    GIORGETTI M,PASSERINI S,SMYRL W H,et al. In situ X-ray absorption spectroscopy characterization of V2O5 xerogel cathodes upon lithium intercalation[J]. Journal of the Electrochemical Society,1999,146(7):2387-2392.
    [12]
    PEULTIER J,ROCCA E,STEINMETZ J. Zinc carboxylating:a new conversion treatment of zinc[J]. Corrosion Science,2003,45(8):1703-1716.
    [13]
    TAKAYA M. Selactive determination method for vanadium (Ⅴ) and vanadium (Ⅳ) controlling the pH of media for a solid-liquid extraction column[J]. Industrial Health,2000,38(1):91-94.
    [14]
    IMTIAZ M,RIZWAN M S,XIONG S L,et al. Vanadium,recent advancements and research prospects:a review[J]. Environment International,2015(80):79-88.
    [15]
    WILLSKY G R,GOLDFINE A B,KOSTYNIAK P J,et al. Effect of vanadium (Ⅳ) compounds in the treatment of diabetes:in vivo and vitro studies with vanadyl sulfate and bIs (maltolato) oxovandium(Ⅳ)[J]. Jounal of Inorganic Biochemistry,2001m85(1):33-42.
    [16]
    WANG P,DONG X C,SCHAEFER D W. Struture and water-barrier properties of vanadate-based corrosion inhibitior films[J]. Corrosion Science,2010,52(3):943-949.
    [17]
    ABDEL S H,BUTT D P. Novel anti-corrosion nano-sized vanadia-based thin films prepared bysol-gel method for aluminum alloys[J]. Journal of Materials Processing Technology,2007,181(1/2/3):76-80.
    [18]
    ZOU Z L,LI N,LI D Y. Progress in research on vanadate-based coatings on corrosion resistance[J]. Journal of Rare Earths,2007,25(S1):303-307.
    [19]
    MOULDER J M F,STICKLE W F,SOBOL W F,et al. Handbook of X-ray photoelectron spectroscopy[M]. Eden Prairie:Perkin-Elmer Corporation,1992.
    [20]
    YANG K H,GER M D,WU W H H,et al. Study of vanadium-based chemical conversion coating on the corrosion resistance of magnesium alloy[J]. Materials Chemistry and Physics,2007,101(2/3):480-485.
    [21]
    POST K,ROBINS R G. Thermodynamic diagrams for the vanadium-water system at 298.15K[J]. Electrochimica Acta,1976,21(6):401-405.
    [22]
    IANNUZZI M,KOVAC J,FRANKEL GS. A study of the mechanisms of corrosion inhibition of AA2024-T3by vanadates using the split cell technique[J]. Electrochimica Acta,200752(12):4032-4042.
    [23]
    IANNUZZI M,YOUNG T,FRANKEL G S. Aluminum alloy corrosion inhibition by vanadates[J]. Journal of the Electrochemical Society,2016,153(12):B533-B541.
    [24]
    IANNUZZI M,FRANKEL G S. Mechanisms of corrosion inhibition of AA2024-T3 by vanadates[J]. Corrosion Science,2007,49:2371-2391.
    [25]
    NITEEN J,MARK B J,VICTORIA G. Tungstate and vanadate-doped polypyrrole/aluminum flakecomposite coatings for the corrosion protection of aluminum 2024-T3[J]. Coat Technol Res,2015,12(2):259-276.

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