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DUAN Zhen-gang, ZHANG Le-fu, JIANG Su-qing, XU Xue-lian, SHI Xiu-qiang. XPS Analysis of Effect of Zinc Addition on Oxide Film on Alloy 800[J]. Corrosion & Protection, 2014, 35(3): 224-227.
Citation: DUAN Zhen-gang, ZHANG Le-fu, JIANG Su-qing, XU Xue-lian, SHI Xiu-qiang. XPS Analysis of Effect of Zinc Addition on Oxide Film on Alloy 800[J]. Corrosion & Protection, 2014, 35(3): 224-227.

XPS Analysis of Effect of Zinc Addition on Oxide Film on Alloy 800

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  • Received Date: May 14, 2013
  • The effects of zinc addition on the composition of the oxide film on alloy 800 were investigated in simulated pressurized water reactor(PWR) primary water. After exposed in solutions with zinc concentration of 0 and 150 μg/kg for 1 500 h, the oxide films developed on the surface of specimens were analyzed using X-ray photoelectron spectroscopy (XPS). Alloy 800 surface formed a duplex oxide film composed of a Ni-riched outer layer and a Cr-riched inner layer, and Fe-poor in two layers in both solutions. In Zn-injected solution, the original atomic concentration of Zn was 17%, and Zn replaced the Mn2+ in the oxide film more obviously.
  • [1]
    HARROD D, GOLD R, JACKO R. Alloy optimization for PWR steam generator heat-transfer tubing[J]. Journal of the Minerals, Metals and Materials Society,2011, 53(7): 14-17.
    [2]
    HUA J B,LI X H,HAN E H,et al. Influence of Zn on oxide films on alloy 690 in borated and lithiated high temperature water[J]. Corrosion Science,2011,53:3254-3261.
    [3]
    MACHET A,GALTAYRIES A,MARCUS P,et al. XPS study of oxides formed on nickel-base alloys in high-temperature and high-pressure water[J]. Surface and interface Analysis,2002,34(1):197-200.
    [4]
    姜苏青,张乐福. 锌对镍基690合金均匀腐蚀影响的XPS分析[J]. 原子能科学技术,2012,3:268-271.
    [5]
    王力,张乐福,石秀强. 压水堆条件下锌对690合金表面氧化膜的影响[J]. 腐蚀与防护,2012,12:1042-1044+1090.
    [6]
    郦晓慧,王俭秋,韩恩厚,等. 核级商用690合金和800合金在模拟压水堆核电站一回路高温高压水中的腐蚀行为研究[J]. 金属学报,2012(8):941-950.
    [7]
    STELLWAG B. The mechanism of oxide film formation on austenitic stainless steels in high temperature water[J]. Corrosion Science,1998,40:337-370.
    [8]
    ROBERTSON J. The mechanism of high temperature aqueous corrosion of stainless steels[J]. Corrosion Science,1991,32(4):443-465.

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