• 中国核心期刊(遴选)数据库收录期刊
  • 中国科技论文统计源期刊
  • 中国学术期刊综合评价数据库来源期刊
Advanced Search
YI De-lian, WANG Jing, LI Yu-peng, LIU Min, WU Lin, PANG Kuan, DOU Bing-qian, LI Min-min. Composite Passivation Technology for Galvanized Steel[J]. Corrosion & Protection, 2010, 31(2): 142-145.
Citation: YI De-lian, WANG Jing, LI Yu-peng, LIU Min, WU Lin, PANG Kuan, DOU Bing-qian, LI Min-min. Composite Passivation Technology for Galvanized Steel[J]. Corrosion & Protection, 2010, 31(2): 142-145.

Composite Passivation Technology for Galvanized Steel

More Information
  • Received Date: April 04, 2009
  • In order to replace the toxic chromate passivation,a composite passivation film was prepared on the galvanized steel by tracking the hydrolysis process of vinyl triethoxy silane(A-151) via conductivity tests and then adding the hydrolysis solution into the basic passivation bath.The corrosion resistance and mechanism of the composite passivation film were studied by neutral salt spray tests (NSS),polarization curve tests and electrochemical impedance spectroscopy (EIS).SEM/EDS were used to analyze the appearance and elements of passivated galvanized steel.The NSS results show that the corrosion area percentage of treated samples was only 4% after 72 h NSS.The SEM/EDS results indicate that a film about 8μm was formed on the galvanized steel,and the constitutes were Si,Mo,P and O.The composite passivation film blocks the anodic reaction of corrosion process.EIS results show that the total impedance of the composite film at the lowest frequency increased by more than one order of magnitude compared with the galvanized steel.
  • [1]
    W J van Ooij.Metal substrate with enhanced corrosion resistance and improved paint adhension[P].US:5455080,1995-10-3.
    [2]
    W J van Ooij.Metal substrate with enhanced corrosion resistance and improved paint adhension[P].US:5539031,1996-7-23.
    [3]
    Zhu D Q,Ooij W J.Corrosion protection of AA-2024-T3 by bis-[3-(triethoxysilyl)propy]-tetrasulfide in neutral sodium shloride solution.Part 1: corrosion of AA 2024-T3[J].Corrosion Science,2003,45:2163-2175.
    [4]
    Zhu D Q,Ooij W J.Corrosion protection of AA-2024-T3 by bis-[3-(triethoxysilyl)propy]-tetrasulfide in neutral sodium shloride solution.Part 2: mechanism for corrosion protection[J].Corrosion Science,2003,45:2177-2197.
    [5]
    Palanivel V,Zhu D Q,Ooij W J.Nanoparticle-filled silane films as chromated replacements for aluminum alloys[J].Progress in Organic Coatings,2003,47:384-392.
    [6]
    王静,伍林,宋世红,等.镀锌层无铬钝化膜耐蚀性研究[J].材料保护,2008,41(11):28-30.
    [7]
    徐溢,王 楠,张小凤,等.直接用作金属表面新型防护涂层的硅烷偶联剂水解效果分析[J].腐蚀与防护,2000,21(4):157-159.
    [8]
    吴海江,卢锦堂,陈锦虹.热镀锌钢表面硅烷膜耐蚀性能的初步研究[J].腐蚀与防护,2006,27(1):13-16.

Catalog

    Article views (3) PDF downloads (3) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return